描述
开 本: 16开纸 张: 胶版纸包 装: 精装是否套装: 否国际标准书号ISBN: 9787122343079
1.内容全面，符合我国当前发展重点，内容涉及资源高效清洁转化及多级循环利用集成技术和绿色过程工程研究成果的回顾、总结与展望。
2.参考性强，本书对于工业绿色清洁发展相关从业人员具有重要的指导意义，对学科发展也大有裨益。
3.作者张懿院士是我国清洁生产研究领域主要开拓者之一，本书收录了作者及其团队在绿色过程工程与清洁生产技术方面成果，共计130余篇代表性学术论文。
本书选登了中国科学院过程工程研究所张懿院士的130余篇学术论文，内容分为总论、亚熔盐绿色化工冶金平台技术、重化工业环境污染治理技术与工程、热点与前沿领域四大主题。本书还附有张懿院士的照片资料、学术成长经历及学术成就、承担的主要科研项目、主要获得奖励和社会兼职等内容，展示了张懿院士科学研究、学术交流及培育人才的经历与成就。
本书充分反映了张懿院士在绿色过程工程方面做出的学术贡献，可供从事绿色化工的科研人员、技术人员参考，也可供高等学校化学工程与工艺、环境科学与工程及相关专业师生参阅。
第1章总论
绿色过程工程
张懿2
SUB-MOLTEN SALT ENVIRONMENTALLY BENIGN TECHNOLOGY
Yi ZHANG, Zuo-Hu LI, Hong-Bin XU, Shi-Li ZHENG, Tao QI, Hui-Quan LI8
绿色化学与铬盐工业的新一代产业革命
张懿，李佐虎，王志宽，陈家镛18
新一代资源回收·循环集成技术与生态化产业体系
张懿，陈家镛，刘会洲26
清洁生产与循环经济
张懿30
原子经济性
张懿36
绿色制造技术发展趋势
张懿，徐滨士，段广洪43
第2章亚熔盐绿色化工冶金平台技术
2.1亚熔盐绿色过程基础49
Comparison of the Oxygen Reduction Reaction between NaOH and KOH Solutions on a
Pt Electrode: The Electrolyte-Dependent Effect
Wei Jin,Hao Du, Shili Zheng,Hongbin Xu, and Yi Zhang49
The influence of KOH concentration, oxygen partial pressure and temperature on
the oxygen reduction reaction at Pt electrodes
Wen-Yi Yan, Shi-Li Zheng, Wei Jin, Zhong Peng, Shao-Na Wang, Hao Du, Yi Zhang63
Structure and Diffusivity of Oxygen in Concentrated Alkali-Metal Hydroxide
Solutions: A Molecular Dynamics Simulation Study
L Ye-Qing,ZHENG Shi-Li,WANG Shao-Na,DU Hao， ZHANG Yi81
Indirect Electrochemical Cr(Ⅲ) Oxidation in KOH
Solutions at an Au Electrode: The Role of Oxygen Reduction Reaction
Wei Jin, Michael S. Moats, Shili Zheng,Hao Du,Yi Zhang, and Jan D. Miller97
Improved electrochemical Cr(Ⅵ) detoxification by
integrating the direct and indirect pathways
Wei Jin, Hao Du, Kai Yan, Shili Zheng, Yi Zhang109
Electrochemical Cr(Ⅲ) Oxidation and Mobilization by In
Situ Generated Reactive Oxygen Species in Alkaline Solution
Yudong Xue,Wei Jin, Hao Du, Shili Zheng,Zhi Sun, Wenyi Yan, and Yi Zhang117
Vibrational spectra and molecular dynamics of hydrogen peroxide molecules at
quartz/water interfaces
Ye-qing Lv, Shi-li Zheng, Shao-na Wang, Wen-yi Yan, Yi Zhang, Hao Du130
Effect of microbubble diameter, alkaline concentration and temperature on
reactive oxygen species concentration
Xiaobin Yu, Zhonghang Wang,Yeqing Lv, Shaona Wang,Shili Zheng, Hao Du， and Yi Zhang148
Electrochemical detoxification and recovery of spent SCR catalyst by insitu
generated reactive oxygen species in alkaline media
Yudong Xue, Yang Zhang, Ying Zhang, Shili Zheng, Yi Zhang, Wei Jin162
Electrochemical enhanced oxidative decomposition of chromite ore in highly
concentrated KOH solution
Zhonghang Wang, Hao Du, Shaona Wang, Shili Zheng, Yi Zhang, Seyeon Hwang, Nam
Soo Kim,Tae Eui Jeong180
Electrochemical decomposition of vanadium slag in concentrated NaOH solution
Zhonghang Wang, Shili Zheng, Shaona Wang, Yaling Qin, Hao Du, Yi Zhang199
Phase Diagram for the System Na2O-Al2O3-H2O at High Alkali Concentration
Yifei Zhang, Yinghui Li, and Yi Zhang211
Phase diagram for the Na2O-Al2O3-H2O system at 130℃
Shuhua Ma,Shili Zheng,Yifei Zhang，and Yi Zhang218
Solubility Data for the NaOH-NaNO3-Na3VO4-Na2CrO4-H2O System at (40 and 80) ℃
Shaona Wang, Ziwei Song, Yan Zhang, Hao Du, Shili Zheng,and Yi Zhang224
Phase Equilibria in the NaOH-Na2MoO4-Na2SO4-H2O System at (313.15 and 403.15) K
Yan Liu, Yifei Zhang, Fangfang Chen, and Yi Zhang232
Isopiestic Study of the Na2CrO4-H2O System at 353.15K: Prediction of the
Solubility of Na2CrO4 in Aqueous NaOH Solutions
Wei Jin, Shili Zheng, Hao Du, Hongbin Xu, and Yi Zhang241
Potential—pH diagrams of Cr-H2O system at elevated
temperatures
YOU Hai-xia, XU Hong-bin, ZHANG Yi, ZHENG Shi-li, GAO Yi-ying250
Vapor Pressure Determination of the KOH K2CrO4 H2O System
Shaona Wang,Shili Zheng,Hong-Bin Xu,and Yi Zhang259
Density and viscosity of aqueous solution of K2CrO4/KOH mixed electrolytes
GUO Ya-jie, XU Hong-bin, GUO Fen,ZHENG Shi-li, ZHANG Yi265
Solid-Liquid Equilibria of K2CO3 K2CrO4 H2O System
Chunhua Du,Shili Zheng,Huiquan Li,and Yi Zhang272
Hydrodynamics of a Multi-Stage Internal Loop Airlift Reactor
Shaoguo Li， Tao Qi， Yi Zhang， Changhou Liu278
Experimental investigation and CFD simulation of liquid-solid-solid dispersion
in a stirred reactor
Licheng Wang, Yifei Zhang, Xingang Li, Yi Zhang288
Na2O-CrO3-Al2O3-H2O四元水盐体系高碱区相图
邹兴，张懿312
Na2CrO4-(NH4)2CrO4-H2O体系的相图
崔金兰，张懿，刘昌见317
Pitzer模型对Na ‖CrO2-4，HCO-3-H2O体系的溶解度计算与实验验证
刘昌见，张懿323
开发用于辅助流程模拟的物性数据库
王兵，赵岩，齐涛，张懿327
2.2铬盐清洁工艺与集成技术337
Green Manufacturing Process of Chromium
Compounds
Yi Zhang, Zuo-Hu Li, Tao Qi, Shi-Li Zheng, Hui-Quan Li, and Hong-Bin Xu337
Green chemistry of chromate cleaner production
ZHANG Yi,LI Zuo-Hu，QI Tao,WANG Zhi-Kuan,ZHENG Shi-Li349
Green metallurgical processing of chromite
S. Zheng, Y. Zhang, Z. Li, T. Qi, H. Li, H. Xu358
Oxidative leaching of a Vietnamese chromite ore in highly concentrated
potassium hydroxide aqueous solution at 300℃ and
atmospheric pressure
H.-B. Xu, S.-L. Zheng, Y.Zhang, Z.-H. Li, Z.-K. Wang368
A New Method of Potassium Chromate Production from Chromite and KOH-KNO3-H2O
Binary Submolten Salt System
Zhi Sun, Yi Zhang, and Shi-Li Zheng,Yang Zhang384
Effect of mechanical activation on alkali leaching of chromite ore
ZHANG Yang, ZHENG Shi-li, DU Hao, XU Hong-bin, ZHANG Yi404
Hydrogen Reduction: A Novel Method of Synthesizing Ultra-fine Chromic Oxide
Powder
BAI Yulan, XU Hongbin, ZHANG Yi411
An investigation on the kinetics of chromium dissolution from Philippine
chromite ore at high oxygen pressure in KOH sub-molten salt solution
Gang Chen, Jiajun Wang, Wang Xiaohui, Shi-Li Zheng, Hao Du, Yi Zhang417
铬铁矿液相氧化过程中材质腐蚀性能研究
郑诗礼，张懿435
铬酸钠氢还原反应动力学
尤海侠，徐红彬，张懿，李佐虎，郑诗礼，白玉兰441
低温氢还原活化烧结法制备氧化铬绿颜料
李平，徐红彬，张懿，李佐虎，郑诗礼448
铬盐清洁生产工艺中铝硅的脱除
王少娜，郑诗礼，张懿454
铬渣零排放绿色化工新过程
齐涛，张懿，郭跃华，李佐虎，王志宽463
2.3钒钛清洁工艺469
Decomposition of ilmenite by concentrated KOH solution under atmospheric
pressure
Yumin Liu, Tao Qi, Jinglong Chu, Qijie Tong, Yi Zhang469
A novel preparation of titanium dioxide from titanium slag
Yongjie Zhang, Tao Qi, Yi Zhang477
Extraction behaviours of titanium and other impurities in the decomposition
process of ilmenite by highly concentrated KOH solution
Yu-min Liu, Hua Lü, Tao Qi, and Yi Zhang487
A novel method of leaching vanadium from extracted vanadium residue using
sodium sub-molten salt medium
Lanjie Li, Shili Zheng, Donghui Chen, Shaona Wang, Hao Du,Minglei Gao, and Yi
Zhang496
A Novel Method to Extract Vanadium and Chromium from Vanadium Slag using Molten
NaOH-NaNO3 Binary System
Biao Liu,Hao Du, Shao-Na Wang, Yi
Zhang, and Shi-Li Zheng,Lan-Jie Li Dong-Hui
Chen506
Kinetics analysis of decomposition of vanadium slag by KOH sub-molten salt
method
Hui-bin LIU, Hao DU, Da-wei WANG, Shao-na WANG, Shi-li ZHENG, Yi ZHANG526
Intensified decomposition of vanadium slag via aeration in concentrated NaOH
solution
Longjie Liu, Zhonghang Wang, Hao Du, Shili Zheng, Ulla Lassi, Yi Zhang543
Crystallization and Separation of Potassium Vanadate in Highly Concentrated
Potassium Hydroxide Solution
Na Yang,Shili Zheng,Shaona Wang,Yaling Qin,Wanli Xie,Bingjing Zhou, and Yi
Zhang558
The electrowinning of vanadium oxide from alkaline solution
Biao Liu, Shili Zheng, Shaona Wang, Yi Zhang, Hao Du566
Cleaner production of vanadium oxides by cation-exchange membrane-assisted
electrolysis of sodium vanadate solution
Bo Pan, Wei Jin, Biao Liu, Shili Zheng, Shaona Wang, Hao Du, Yi Zhang579
Vanadium metabolism investigation using substance flow and scenario analysis
Fangfang ZHANG, Huiquan LI, Bo CHEN, Xue GUAN, Yi ZHANG593
KOH亚熔盐法制备钛酸钾晶须和二氧化钛
仝启杰，齐涛，刘玉民，王丽娜，张懿609
活性炭强化氧化亚熔盐介质中钒渣分解机理
王少娜，王亚茹，杜浩，郑诗礼，张懿617
2.4氧化铝、钽铌清洁工艺及其他629
Spectra of sodium aluminate solutions
MA Shu-hua, ZHENG Shi-li, XU Hong-bin,ZHANG Yi629
Preparation of sodium aluminate from the leach liquor of diasporic bauxite in
concentrated NaOH solution
Shaotao Cao, Yifei Zhang, Yi Zhang637
Nucleation and Morphology of Monosodium Aluminate Hydrate from Concentrated
Sodium Aluminate Solutions
Shaotao Cao, Yifei Zhang, and Yi Zhang650
Research on NaCaHSiO4 decomposition in sodium hydroxide solution
Ran Zhang, Shuhua Ma, Quancheng Yang, Shili Zheng, Yi Zhang, Namsoo Kim, Sungik
Hong661
Additives effects on crystallization and morphology in a novel caustic
aluminate solution decomposition process
Ying ZHANG, Shili ZHENG, Yifei ZHANG, Hongbin XU, Yi ZHANG679
Cleaner synthesis of mesoporous alumina from sodium aluminate solution
Li Zhong, Yifei Zhang, and Yi Zhang686
Combined treatment of red mud and coal fly ash by a hydro-chemical process
Chunli Liu, Shuhua Ma, Shili Zheng,Yang Luo, Jian Ding, Xiaohui Wang, Yi
Zhang698
Study of extracting alumina from high-alumina PC fly ash bya hydro-chemical
process
Jian Ding, Shuhua Ma, Shili Zheng, Yi Zhang, Zongli Xie, Shirley Shen, Zhongkai
Liu714
Leaching of a low-grade niobium-tantalum ore by highly concentrated caustic
potash solution
Hongming Zhou, Shili Zheng, Yi Zhang730
Kinetic Investigations on the Leaching of Niobium from a Low-Grade
Niobium-Tantalum Ore by Concentrated KOH Solution
ZHOU Hongming，ZHENG Shili, and ZHANG Yi739
Dissolution behaviors of Ta2O5, Nb2O5 and their mixture in KOH and H2O system
WANG Xiao-hui, ZHENG Shi-li, XU Hong-bin, ZHANG Yi750
A novel method to prepare ultrafine potassium tantalate powders
Xiaohui Wang, Shili Zheng, Yi Zhang760
Dehydration of tetrahydrate potassium pentaborate in fluidized bed
Gang Yang, Zuohu Li, Yi Zhang765
Preparation and surface chemistry characteristics of pure and coated acicular α-FeOOH particles
Guo Yue-Hua, Zhang Yi773
铝酸钠溶液中过饱和氧化硅的稳定性
张亦飞，郑诗礼，张懿782
NaOH亚熔盐法处理拜尔法赤泥的铝硅行为
孙旺，郑诗礼，张亦飞，徐红彬，张懿787
一水硬铝石型铝土矿在KOH亚熔盐介质中的溶出行为
马青霞，张亦飞，曹绍涛，张懿794
高苛性化系数铝酸钠溶液深度脱硅
元炯亮，张懿804
甲醇溶析铝酸钠制备氢氧化铝
王雪，郑诗礼，张懿809
第3章重化工业环境污染治理技术与工程
3.1工业废水治理技术818
Recovery of heavy metals from electroplating sludge and stainless steel pickle
waste liquid by ammonia
leaching method
Zhang Yi，Wang Zhi-kuan，Xu Xia，Chen Yong-qi，Qi Tao818
Electrochemical dechlorination of chloroacetic acids(CAAs) using
hemoglobin-loaded carbon nanotube
electrode
Yu-Ping Li, Hong-Bin Cao, Yi Zhang823
Electrochemical reduction of nitrobenzene at carbon nanotube electrode
Yu-Ping Li, Hong-Bin Cao, Chen-Ming Liu, Yi Zhang831
A novel mechanism of bisphenol A removal during electro-enzymatic oxidative
process: Chain reactions from self-polymerization to cross-coupling oxidation
Haitao Li, He Zhao, Chenming Liu, Yuping Li,Hongbin Cao, Yi Zhang843
Novel technique for internal structure and elemental distribution analyses of
granular sludge from reactors for wastewater treatment
Xiaolei Cao，Hongbin Cao，Yuxing
Sheng，Haixia You, Yi Zhang857
Optimal Design of Solvent Blend and Its Application in Coking Wastewater
Treatment Process
Mingsen Liao, Yuehong Zhao, Pengge Ning,Hongbin Cao,Hao Wen, and Yi Zhang864
Activated carbon-enhanced ozonation of oxalate attributed to HO·oxidation in bulk solution and surface oxidation:Effects of the type
and number of basic sites
Linlin Xing, Yongbing Xie, Hongbin Cao, Daisuke Minakata, Yi Zhang, John C.
Crittenden882
Desalination stability of capacitive deionization using ordered mesoporous
carbon: Effect of oxygen-containing surface groups and pore properties
Feng Duan, Xuan Du, Yuping Li, Hongbin Cao, Yi Zhang900
Activated carbon electrodes: Electrochemical oxidation coupled with
desalination for wastewater treatment
Feng Duan, Yuping Li, Hongbin Cao,Yi Wang, John C. Crittenden, Yi Zhang915
C3N4-Mn/CNT composite as a heterogeneous catalyst in the electro-peroxone
process for promoting the reaction between O3 and H2O2 in acid solution
Zhuang Guo, Linbi Zhou, Hongbin Cao，Yongbing Xie，Jiadong Xiao，Jin Yang, and Yi Zhang927
基于MINLP 模型的焦化废水蒸氨塔操作优化
廖明森，赵月红，宁朋歌，曹宏斌，温浩，张懿943
新型非均相电-Fenton 技术深度处理焦化废水
李海涛，李玉平，张安洋，曹宏斌，李鑫钢，张懿955
3.2工业固废资源化966
Preparation of high purity magnesium oxide and magnetic ferrite from chromium
containing residue I. Mathematical model and experiments under atmospheric
carbonate leaching
Tao Qi，Yi Zhang，Yuehua Guo，Zuohu Li966
Preparation of high purity magnesium oxide and magnetic ferrite from chromium
containing residue Ⅱ. Pressurized carbonate leaching
and preparation of magnetic ferrite
Yuehua Guo，Tao Qi，Yi Zhang，Zuohu Li，Jiashu Liu971
Preparation of monodispersed aragonite microspheres via a carbonation
crystallization pathway
Weijun Bao, Huiquan Li, and Yi Zhang976
Selective extraction and deep removal of tungsten from sodium molybdate
solution by primary amine N1923
Pengge Ning, Hongbin Cao, Yi Zhang985
Separation of copper, iron(Ⅲ), zinc and nickel from
nitrate solution by solvent extraction using LK-C2
Xiaojuan Zhang, Xingang Li, Hongbin Cao, Yi Zhang999
Effects of various pretreatments on biological sulfate reduction with waste
activated sludge as electron donor and
waste activated sludge diminution under biosulfidogenic condition
Yuxing Sheng, Hongbin Cao, Yuping Li, Yi Zhang1014
Experimental investigation of enhanced carbonation by solvent extraction for
indirect CO2 mineral sequestration
Weijun Bao, Huiquan Li, and Yi Zhang1028
A novel process for recycling and resynthesizing LiNi1/3Co1/3Mn1/3O2 from the
cathode scraps intended for lithium-ion batteries
Xihua Zhang, Yongbing Xie, Hongbin Cao，Faheem Nawaz, Yi
Zhang1050
Selective extraction and deep separation of V(Ⅴ)
and Cr(Ⅵ) in the
leaching solution of chromium-bearing vanadium slag with primary amine LK-N21
Pengge Ning, Xiao Lin, Hongbin Cao, Yi Zhang1068
The influence of impurities on Ga electrowinning:Vanadium and iron
Ling Liu, Mingyong Wang, Zhi Wang, Yi Zhang1082
Insights into the extraction of various vanadium species by primary amine
Jiawei Wen，Feng Liu, Hongbin Cao,Pengge Ning, Yi
Zhang1094
Spent lead-acid battery recycling in China-A review and sustainable analyses on
mass flow of lead
Zhi Sun, Hongbin Cao, Xihua Zhang, Xiao Lin,Wenwen Zheng, Guoqing Cao, Yong
Sun,Yi Zhang1105
Lithium Carbonate Recovery from Cathode Scrap of Spent Lithium-Ion Battery: A
Closed-Loop Process
Wenfang Gao, Xihua Zhang, Xiaohong Zheng,Xiao Lin,Hongbin Cao,Yi Zhang,Zhi
Sun1125
Selective recovery of valuable metals from spent lithium-ion batteries—Process development and kinetics evaluation
Wenfang Gao, Jiali Song, Hongbin Cao,Xiao Lin, Xihua Zhang,Xiaohong Zheng, Yi
Zhang, Zhi Sun1141
Evaluation on end-of-life LEDs by understanding the criticality and
recyclability for metals recycling
Sheng Fang, Wenyi Yan, Hongbin Cao,Qingbin Song, Yi Zhang, Zhi Sun1166
Selective recovery of lithium from spent lithium iron phosphate batteries: a
sustainable process
Yongxia Yang，Xiangqi Meng，Hongbin
Cao，Xiao Lin，Chenming Liu，Yong Sun，Yi Zhang，Zhi
Sun1188
A promising approach to recover a spent SCR catalyst: Deactivation by arsenic
and alkaline metals and catalyst regeneration
Meng Li, Biao Liu, Xinran Wang, Xiaobin Yu, Shili Zheng,Hao Du, David
Dreisinger,Yi Zhang1210
第4章热点与前沿领域
4.1新型功能材料研发1226
The effect of electrolytic oxidation on the electrochemical properties of
multi-walled carbon nanotubes
Chen-Ming Liu,Hong-Bin Cao, Yu-Ping Li,Hong-Bin Xu,Yi Zhang1226
Reductive dehalogenation of haloacetic acids by hemoglobin-loaded carbon
nanotube electrode
Yu-Ping Li, Hong-Bin Cao, Yi Zhang1236
Promoting effect of nitration modification on activated carbon in the catalytic
ozonation of oxalic acid
Hongbin Cao, Linlin Xing, Guangguo Wu, Yongbing Xie,Shaoyuan Shi, Yi Zhang,
Daisuke Minakata, John C. Crittenden1250
m-BiVO4 hollow spheres coated on carbon fiber with superior reusability as
photocatalyst
Toheed Ahmed,Hong-ling Zhang, Hong-bin Xu, Yi Zhang1266
The corrosion resistance of Ni anode and Ga electrowinning in alkaline sulfide
solutions
Ling Liu，Mingyong Wang，Zhi Wang，Yi Zhang1281
Amino-modification and successive electrochemical reduction of graphene oxide
for highly sensitive electrochemical detection of trace Pb2
Mingjie Li, Zehui Li, Chenming Liu, Yu Chang,Jiawei Wen, He Zhao,Hongbin Cao,
Yi Zhang, Dagang Liu1295
Amorphous-crystalline TiO2/carbon nanofibers composite electrode by one-step
electrospinning for symmetric supercapacitor
Kexin Tang，Yuping Li, Hongbin Cao，Chunlei Su，Zisheng Zhang，Yi Zhang1309
Macropore-and Micropore-Dominated Carbon Derived from Poly(vinyl alcohol) and
Polyvinylpyrrolidone for Supercapacitor and Capacitive Deionization
Kexin Tang，Junjun Chang, Hongbin Cao，Chunlei Su，Yuping Li，Zisheng Zhang，and Yi Zhang1329
High-Rate and Long-Term Cycle Stability of Li-S Batteries Enabled by
Li2S/TiO2-Impregnated Hollow Carbon Nanofiber Cathodes
Xinran Wang，Xuanxuan Bi Shaona Wang，Yi Zhang,Hao Du，and Jun Lu1346
High-Rate Performance and Ultralong Cycle Life Enabled by Hybrid
Organic-Inorganic Vanadyl Ethylene Glycolate for Lithium-Ion Batteries
Xinran Wang，Xuanxuan Bi，Shili
Zheng，Shaona Wang，Yi Zhang，Hao Du，and Jun Lu1361
Preparation of CrO2 nanoparticles via oxidation method
Zhenzhao Pei，Hongbin Xu，Yi
Zhang1377
Preparation of Cr2O3-based pigments with high NIR reflectance via thermal
decomposition of CrOOH
Shu-ting LIANG,Hong-ling ZHANG,Min-ting LUO,Hong-xia LIU,Yu-lan BAI,Hong-bin
XU,Yi ZHANG1383
Synthesis,Characterization,and Boron Uptake of Organic-Inorganic Hybrid Mesoporous Materials
Lina Wang,Tao Qi, and Yi Zhang1394
Influences of processing techniques of the H2O2-precipitated pseudoboehmite on
the structural and textural properties of γ-Al2O3
Weiquan Cai,Huiquan Li,Yi Zhang1399
Properties of Water Blown Rigid Polyurethane Foams with Different Functionality
LI Xiaobin,CAO Hongbin,ZHANG Yi1412
The vanadate adsorption on a mesoporous boehmite and its cleaner production
application of chromate
Ping Li,Sili Zheng,Penghui Qing,Yongan Chen,Lei Tian,Xiaodan Zheng,and Yi
Zhang1421
Porous hexagonal boron nitride nanosheets with large adsorption capacity for
Cu2 synthesized through a two-step roasting process
Jing Zhang,Hong-ling Zhang,Peng Zhou,Peng-hui Qing,Hong-bin Xu,Yi Zhang1436
碳酸盐热解法制备氧化镁晶须
王万平, 张懿1442
4.2绿色催化与循环经济1446
Preparation of monodispersed aragonite microspheres via a carbonation
crystallization pathway
Weijun Bao,Huiquan Li,and Yi Zhang1446
A non-phosgene route for synthesis of methylene diphenyl dicarbamate from
methylene dianiline and methyl carbamate
Yixia Pei,Huiquan Li,Haitao Liu,Yi Zhang 1455
Non-phosgene synthesis of isocyanates based on CO2: Synthesis of methyl N-phenyl
carbamate through coupling route with lead compound catalysts
Junjie Gao,Huiquan Li,Yi Zhang,Weiyang Fei1464
Variations of Structure and Active Species in Mesoporous Cr-MSU-x Catalyst
during the Dehydrogenation of Ethane with CO2
L.-Ch.Liu,H.-Q. Li, and Y.Zhang1474
Oxidative Dehydrogenation of Ethane to Ethylene with CO2 over Fe-Cr/ZrO2
Catalysts Shuang Deng,Songgeng Li,Huiquan Li,and Yi Zhang1485
Energy conservation and circular economy in China’s
process industries
Huiquan Li,Weijun Bao,Caihong Xiu,Yi Zhang,Hongbin Xu 1496
Insights on the mechanism for synthesis of methylenedianiline from aniline and
formaldehyde through HPLC-MS and isotope tracer studies
Chen Ye Wang,Hui Quan Li,Li Guo Wang,Yan Cao,Hai Tao Liu,Yi Zhang 1513
钢铁生产流程污染贡献综合评价方法研究
修彩虹，李会泉，张懿1519
Bu2SnO催化反应耦合法清洁合成苯氨基甲酸甲酯
高俊杰，李会泉，张懿，费维扬1525
Cr/MSU-1催化剂中Cr含量对CO2氧化丙烷脱氢反应催化性能的影响
柳海涛，李会泉，杨玮娇，王兴瑞，张懿1535
循环型过程工业系统设计——框架、策略与案例研究
李会泉，齐涛，郑诗礼，徐红彬，李佐虎，张懿1542
附录
张懿简历1547
学术成长经历及学术成就1548
主要获得的奖励及荣誉1551
主要社会兼职1552
主要论著列表1553
人才培养统计1554
硕士研究生1554
博士研究生1556
博士后1561
化学化工常见非法定计量单位和换算系数1562
张懿院士八十岁华诞来临之际，我们作为张先生的学生和晚辈以十分崇敬的心情编纂了这本论文集精选。
中国工程院院士、环境与过程工程专家张懿是我国绿色过程工程的主要开拓者之一，在国际上首次从生产源头上彻底解决了铬盐行业重金属污染的难题,首次实现了铬渣的零排放和铬资源多组分深度利用的生态工业新模式，为我国国民经济的可持续发展做出了重要贡献。
1939年农历四月二十八日，张懿院士出生在黑龙江省牡丹江市。张懿从小学少先队大队长、初中的尖子生到1955年以优异成绩考取了东北最好的学校辽宁省实验中学高中。张懿院士在确定考大学也是国家需要后，选择了冶金物理化学专业，既有理科的攻坚，又能为东北冶金重工业服务。1958年报考东北工学院（现东北大学）冶金物化专业，以化学工程和物理化学为知识基础解决国民经济主体产业的发展问题。1963年张懿以东北工学院冶金物化全系总分第一名的成绩被学校分配到北京的中国科学院化工冶金研究所（现中国科学院过程工程研究所）陈家镛院士领导的湿法冶金研究室，从此她在中科院国家一流研究所的土壤上，在20世纪50年代回国的著名爱国科学家陈家镛（化学工程专家）、叶诸沛（化工冶金专家）、郭慕孙（化学工程专家）的指导下，在过程工程领域不断开拓创新，逐步建立了可解决我国资源环境瓶颈问题并引领未来发展的系列基础与应用研究的重要科技方向。
张懿院士在环境工程领域做出了开拓性贡献。20世纪80年代初，在工业污染治理社会需求急迫的背景下，张懿院士在国内率先将资源材料化学化工的最新成果和研究方法融合渗透到环境工程研究领域，开拓了资源材料化学化工与环境工程交叉综合研究的新方向，提出资源再生循环与无害化技术相结合的积极治理路线，主持完成了多项国家“七五”“八五”“九五”环保科技攻关及院部级重大项目，在重金属危险废弃物污染控制方向建立了多组分高效选择性提取、Cr(Ⅵ)催化还原水解、萃取分离、铁氧体固定无害化、资源循环利用与酸碱废弃物协同治理等系列新技术和应用工程，建成国内外第一个多组分重金属污泥综合回收生产线。“八五”攻关主持完成的“电镀污泥与铬渣资源化技术”为我国重金属有害废弃物资源化提供了产业化集成技术。近年又完成了钒-铬废渣资源化、冶金行业氨氮废水处理、钢铁焦化行业焦化废水处理等环保难题的十多个产业化应用工程，具有化工过程强化环境治理的鲜明技术创新特色，较传统工艺大幅度提高了处理效率，高效回收资源，降低环境治理成本，获得了国家主管部门和企业的高度认可，为完成国家重点污染物减排指标做出了重要贡献。相关成果获国家奖5项，院部级奖7项，已发挥重大社会效益、环境效益和经济效益，促进了我国工业废弃物治理从消纳性处置提高到资源良性循环的新阶段。
随着时代发展和需求，20世纪90年代初，张懿院士准确把握了国内外资源环境领域技术发展趋势，在绿色过程工程领域做出了开拓性贡献。针对我国重化工业高速发展阶段的资源环境瓶颈问题，在中科院开拓了清洁生产工艺与技术研究新领域，率先由工业污染末端治理转向源头污染控制技术研究。张懿院士主持我国第一个清洁工艺国家攻关和863项目，从铬化工重污染行业切入，在国内外首次提出亚熔盐非常规介质低温高效清洁转化铬、铝、钒、钛、铌、钽、锆等多种两性金属矿产资源的原创性原子经济性反应新系统、新原理，建立了亚熔盐介质中活性氧组分对矿物矿相转化量化调控的理论和物理场协同强化技术，已在铬化工行业取得工业应用并成为国家认定的行业替代性清洁技术。该成果已于2005年获国家技术发明二等奖，为最终实现产业化应用，正在扩展为铝、钒、钛、钽、锆等两性金属亚熔盐清洁工艺的共性技术。该系列产业化集成技术可解决我国大宗特色难处理矿产资源综合利用和过程污染控制的资源-环境难题。
在清洁生产集成技术研究基础上，从企业和系统尺度，在国内最早从技术层面研究工业废弃物与过程物流质量交换集成网络构建的循环经济方法。所指导的“河南义马市循环经济建设规划”“株洲清水塘循环经济工业园区规划”为国家环境保护总局（现生态环境部）和国家发改委审批的国家级循环经济试点。作为国家循环经济规划和工业生态网络构建主要专家，多次主持与参加循环经济规划审定，为推动我国循环经济建设作出了重要奉献。
在绿色化学化工与环境化学基础研究方面，张懿院士发现并定义亚熔盐非常规介质，针对物质转化的化学活化，建立了亚熔盐非常规介质的全新化学、溶液模型与热力学计算方法，首次在分子水平解析亚熔盐介质中不同类型活性氧负离子/原子（O2-、O-2、O2-2、HO-、O等）生成机理及赋存规律，形成“亚熔盐非常规介质高效清洁新过程”的系统理论和共性技术基础研究平台，对推动我国难处理资源高效清洁循环利用与材料研究奠定了重要理论基础。已获得国内外学术界与相关产业界的很高评价与认同，形成基础理论-应用技术-产业开发的良性科研模式。
张懿院士的研究团队获得2002年国家人事部、中国科学院授予的“先进集体”。张懿院士克己奉公，不拿现场补贴，还个人资助合作企业的困难职工，在合作单位树立了共产党员科学家的很高威信。她用自己的实践和人格魅力证实共产党人对科技事业的崇高追求，连续多年被评为中科院和中央国家机关优秀共产党员，2001年被评为中科院首届“十大杰出妇女”。
张懿院士敬业、团结、求实、创新，视名利淡如水，看事业重如山。数十载科研生涯，桃李满天下，春晖遍四方，一直默默为我国的资源环境科学事业忘我耕耘。在张懿院士80岁生日来临之际，编写组特整理了张懿发表的学术论著，精选编纂了这本《绿色过程工程与清洁生产技术》，记录了张懿院士所有的学术思想，在环境工程领域、绿色过程工程领域和工业生态网络构建/工业循环经济建设方面的开拓性贡献，以及在绿色化学化工与环境化学基础研究方面的突出贡献。书中所收录的原论文、发表时间跨度较大，随时代发展，稿件中一些名词术语存在不同用法。为尊重历史原貌、保留原文风格，在文中不做统一、于书后附有非法定计量单位换算表，以供参考。
忆往昔，张懿院士对我们的谆谆教诲。岁月如梭，春秋轮回，衷心祝愿张懿院士：生命之树常绿，生命之水长流！
本书编写组
2019年1月
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